Study on Aging and Life Prediction of Fluoroether Lubricating Grease for Spacecraft
-
摘要: 润滑脂老化性能退化对航天器展开机构、运动部件等运行的可靠性至关重要,但目前针对润滑脂的老化对性能影响及寿命预测的研究相对较少,缺少系统的理论指导航天器长寿命润滑脂的应用.选取质量变化率作为老化失效关键指标,通过应用阿伦尼乌斯方程(Arrhenius equation)和时间-温度关系,得到一个基于润滑脂质量保留率的时间-温度等效模型,可预测润滑脂在各种贮存条件下的质量变化.通过监测滴点、锥入度等关键性能指标的变化来评估其老化性能.研究表明,老化对滴点、锥入度性能影响较大,当润滑脂质量损失率达到1%时,预测失效寿命为5.4 a.同时,利用四球摩擦试验研究了润滑脂在不同载荷下对轴承钢GCr15的摩擦性能.结果表明,在较大载荷条件下,老化对润滑脂摩擦因数与磨斑直径的影响更加显著.研究结果及方法为了解润滑脂老化性能退化及寿命预测研究提供了依据,能够为航天器长寿命润滑脂的选择和优化设计提供理论支撑.Abstract: The lubricating grease degradation and aging performance is critical to the reliability of spacecraft deployment mechanisms, moving components, and other related products. Limited research has been conducted on the effects of grease aging on performance and lifespan prediction, with insufficient theoretical support for the application of long-life lubricating grease in spacecraft. The quality change rate was selected as the key performance for aging failure, a time temperature equivalent model based on the quality retention rate of lubricating grease was obtained by means of the Arrhenius equation and the time temperature relationship, which can predict the quality change of lubricating grease under various storage conditions. Key parameters such as the droplet point and the cone penetration were monitored to evaluate the lubricating grease aging performance. The results show that, aging has a significant impact on the droplet point and the cone penetration performance, with a 1% loss rate of the lubricating grease mass indicating a predicted lifespan of 5.4 a at the failure point. In addition, a 4-ball friction test was used to study the lubricating grease friction performance on bearing steel GCr15 under different loads. The test indicate that aging significantly influences the lubricating grease friction coefficient and the wear zone diameter under high loads. The research results and methods provide a basis for understanding the lubricating grease degradation and aging performance, and predicting its lifespan.
-
Key words:
- fluroether lubricating grease /
- accelerated ageing test /
- shelf-life /
- 4-ball tribometer
edited-byedited-by1) (我刊青年编委田阔推荐) -
表 1 试验材料参数
Table 1. Experimental material parameters
dropping point /℃ cone penetration /(0.1 mm) evaporation capacity(100 ℃)/% oil separation(200 g±2 g)/(%·(m/m)) ≥120 50~70 ≤1 ≤7 表 2 润滑脂滴点实测值
Table 2. Measured values of lubricant drip points
sample description dropping point/℃ 1# 156 2# 157 3# 156 4# 156 5# 157 average value 156 表 3 载荷与摩擦因数、直径关系
Table 3. Relationships between the load, the friction coefficient and the spot diameter
sample friction factor wear-scar /mm 100 N 200 N 300 N 100 N 200 N 300 N non-aged lubricating grease 0.184 0.152 0.123 0.53 0.65 0.57 accelerated aging lubricating grease(140 ℃,90 d) 0.176 0.173 0.153 0.53 0.68 0.77 表 4 润滑脂主要理化参数
Table 4. Main physico-chemical parameters of lubricating greases
parameter grease not aged (storage for 5 a) grease (storage for 5 a) grease not aged (life expectancy prediction of 5.4 a) grease (life expectancy prediction of 5.4 a) dropping point/℃ 157 145 156 143 1/4 cone penetration/(0.1 mm) 60 53 59 52 -
[1] 郑会, 周巍峰, 崔佩娟, 等. 长寿命低挥发性润滑脂的性能研究[J]. 石油炼制与化工, 2024, 55(7): 111-118.ZHENG Hui, ZHOU Weifeng, CUI Peijuan, et al. Investigation on the performance of long-life and low-volatile lubricating grease[J]. Petroleum Processing and Petrochemicals, 2024, 55(7): 111-118. (in Chinese) [2] PEI Z, XU M, CAO J, et al. Analysis of the microcharacteristics of different kinds of asphalt based on different aging conditions[J]. Materials and Structures, 2022, 55(10): 250. doi: 10.1617/s11527-022-02088-3 [3] PENG C, GUO C, YOU Z, et al. The effect of waste engine oil and waste polyethylene on UV aging resistance of asphalt[J]. Polymers (Basel), 2020, 12(3): 602. doi: 10.3390/polym12030602 [4] JING R, VARVERI A, LIU X, et al. Ageing effect on chemo-mechanics of bitumen[J]. Road Materials and Pavement Design, 2021, 22(5): 1044-1059. doi: 10.1080/14680629.2019.1661275 [5] YANG J, ZHU X, YUAN Y, et al. Effects of aging on micromechanical properties of asphalt binder using AFM[J]. Journal of Materials in Civil Engineering, 2020, 32(5): 04020081.1-04020081.11. doi: 10.1061/(ASCE)MT.1943-5533.0003030 [6] TIAN X, LI G, LU X, et al. Study on the short-term aging behavior of asphalt based on PCA and LSM analysis[J]. Journal of Materials in Civil Engineering, 2022, 34(8): 04022181.1-04022181.12. [7] 廖宇, 钟贵勇, 舒茂盛, 等. 激光增材制造金属材料疲劳寿命研究[J]. 应用数学和力学, 2023, 44(2): 201-208.LIAO Yu, ZHONG Guiyong, SHU Maosheng, et al. A study on the fatigue life of the laser additive manufactured metallic material[J]. Applied Mathematics and Mechanics, 2023, 44(2): 201-208. (in Chinese) [8] 范志庚, 万强, 牛红攀, 等. 计及时变演化特征的硅泡沫垫层非线性黏弹性模型研究[J]. 应用数学和力学, 2024, 45(2): 167-174.FAN Zhigeng, WAN Qiang, NIU Hongpan, et al. A nonlinear viscoelastic model for silicon rubber foam cushion considering time-varying evolution characteristics[J]. Applied Mathematics and Mechanics, 2024, 45(2): 167-174. (in Chinese) [9] 张凯, 傅强, 黄渝鸿, 等. 润滑油贮存寿命的预测[J]. 机械工程材料, 2005, 29(10): 44-45.ZHANG Kai, FU Qiang, HUANG Yuhong, et al. Prediction of shelf-life of lubricating oils[J]. Materials for Mechanical Engineering, 2005, 29(10): 44-45. (in Chinese) [10] 朱廷彬. 润滑脂技术大全[M]. 北京: 中国石化出版社, 2009: 57-69.ZHU Tingbin. Complete Collection of Lubricating Greases Technology[M]. Beijing: China Petrochemical Press, 2009: 57-69. (in Chinese) [11] 李芝华, 邬花元, 任冬燕, 等. 高温润滑脂的研究进展[J]. 材料导报, 2004, 18(1): 53-56.LI Zhihua, WU Huayuan, REN Dongyan, et al. Recent progress in research on high temperature lubricant greases[J]. Materials Review, 2004, 18(1): 53-56. (in Chinese) [12] 郭太勤, 蒋明俊, 郭小川, 等. 高温润滑脂的发展现状[J]. 润滑与密封, 2006(1): 164-167.GUO Taiqin, JIANG Mingjun, GUO Xiaochuan, et al. Advancement of high temperature grease[J]. Lubrication Engineering, 2006(1): 164-167. (in Chinese) [13] 郑会, 周巍峰, 崔佩娟, 等. 长寿命低挥发性润滑脂的性能研究[J]. 石油炼制与化工, 2024, 55(7): 111-118.ZHENG Hui, ZHOU Weifeng, CUI Peijuan, et al. Investigation on the performance of long-life and low-volatile lubricating grease[J]. Petroleum Processing and Petrochemicals, 2024, 55(7): 111-118. (in Chinese) [14] 白传航. 润滑脂的组成和性能评价[J]. 合成润滑材料, 2004, 31(1): 35-41.BAI Chuanhang. Ingredients and performance evaluation of grease[J]. Synthetic Lubricants, 2004, 31(1): 35-41. (in Chinese) [15] 张澄清, 李庆德. 润滑脂应用指南[M]. 北京: 中国石化出版社, 1993: 327-329.ZHANG Chengqing, LI Qingde. Lubricating Grease Application Guide[M]. Beijing: China Petrochemical Press, 1993: 327-329. (in Chinese) [16] 王汝霖. 润滑剂摩擦化学[M]. 北京: 中国石化出版社, 1994: 25-30.WANG Rulin. Lubricant Tribochemistry[M]. Beijing: China Petrochemical Press, 1994: 25-30. (in Chinese) [17] 关子杰. 润滑油与设备故障诊断技术[M]. 北京: 中国石化出版社, 2007: 37-38.GUAN Zijie. Lubricating Oil and Equipment Fault Diagnosis Technology[M]. Beijing: China Petrochemical Press, 2007: 37-38. (in Chinese) [18] 杨保利, 吕敏. 密封润滑脂应用性能试验研究[J]. 润滑与密封, 2000, 25(1): 35-37.YANG Baoli, LV Ming. Application property tests on sealing grease[J]. Lubrication Engineering, 2000, 25(1): 35-37. (in Chinese) [19] 李倩, 辛虎, 曹春兰. 改善轴承温升的氟醚润滑脂的制备[J]. 合成润滑材料, 2020, 47(3): 18-20.LI Qian, XIN Hu, CAO Chunlan. Preparation of fluoroether grease to improve bearing temperature rise[J]. Synthetic Lubricants, 2020, 47(3): 18-20. (in Chinese) [20] 张新兰, 陈风波, 王姝瑛, 等. 轴承用有机硅润滑脂贮存寿命评估[J]. 润滑与密封, 2020, 45(6): 125-128.ZHANG Xinlan, CHEN Fengbo, WANG Shuying, et al. Evaluation on shelf life of organosilicon grease for bearings[J]. Lubrication Engineering, 2020, 45(6): 125-128. (in Chinese) [21] 王川, 蒋明俊, 郭小川, 等. 复合钛基润滑脂静态热老化性能的研究[J]. 石油炼制与化工, 2020, 51(3): 73-79.WANG Chuan, JIANG Mingjun, GUO Xiaochuan, et al. Study on static thermal aging properties of titanium complex grease[J]. Petroleum Processing and Petrochemicals, 2020, 51(3): 73-79. (in Chinese) [22] 李秀荣, 潘家保, 王玲娟, 等. 静态热老化对润滑脂皂纤维缠结及恢复性能的影响[J]. 润滑与密封, 2016, 41(12): 93-97.LI Xiurong, PAN Jiabao, WANG Lingjuan, et al. Effect of static thermal ageing on fibrous entanglement and reversibility of lubricating greases[J]. Lubrication Engineering, 2016, 41(12): 93-97. (in Chinese) [23] 黄振雄, 胡萍, 郭阳, 等. 膨润土-复合铝基润滑脂的老化分析[J]. 石油化工, 2018, 47(7): 696-701.HUANG Zhenxiong, HU Ping, GUO Yang, et al. Aging analysis of bentonite-composite aluminum base lubricating grease[J]. Petrochemical Technology, 2018, 47(7): 696-701. (in Chinese) [24] 王德岩, 单慧军. 润滑脂剩余使用寿命的评定技术[J]. 合成润滑材料, 2005, 32(1): 22-24.WANG Deyan, SHAN Huijun. Elevation technique of remaining useful life of grease[J]. Synthetic Lubricants, 2005, 32(1): 22-24. (in Chinese) [25] 李海波, 张正平, 胡彦平. 加速寿命试验方法及其在航天产品中的应用[J]. 强度与环境, 2007, 34(1): 2-10.LI Haibo, ZHANG Zhengping, HU Yanping. Accelerated life testing method and its applications for space products[J]. Structure & Environment Engineering, 2007, 34(1): 2-10. (in Chinese) [26] 周堃, 胡滨, 王津梅, 等. 阿伦尼乌斯公式在弹箭贮存寿命评估中的应用[J]. 装备环境工程, 2011, 8(4): 1-4.ZHOU Kun, HU Bin, WANG Jinmei, et al. Application of Arrhenius equation in storage life evaluation of ammunition[J]. Equipment Environmental Engineering, 2011, 8(4): 1-4. (in Chinese)) -
下载:
渝公网安备50010802005915号